|
|
L-tyrosine + D-ribulose_5-phosphate <=> (2S)-3-(4-hydroxyphenyl)-2-isocyanopropanoate + Hydroxyacetone + phosphate + formaldehyde + H2O + H+
|
4.1.99.24
L-tyrosine isonitrile synthase
|
–
|
M
|
|
BRENDA:
BR52463
KEGG:
R12150
MetaCyc:
RXN-19261
|
|
|
|
L-tryptophan + D-ribulose_5-phosphate <=> (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + Hydroxyacetone + phosphate + formaldehyde + H2O + H+
|
4.1.99.25
L-tryptophan isonitrile synthase
|
–
|
M
|
|
BRENDA:
BR52464
KEGG:
R12151
MetaCyc:
RXN-19264
|
|
|
|
Hydroxyacetone + NADP+ <=> H+ + methylglyoxal + NADPH
|
1.1.1
1.1.1.1
alcohol dehydrogenase
1.1.1.153
sepiapterin reductase (L-erythro-7,8-dihydrobiopterin forming)
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.21
aldose reductase
1.1.1.72
glycerol dehydrogenase (NADP+)
1.3.1.20
trans-1,2-dihydrobenzene-1,2-diol dehydrogenase
|
–
–
–
–
–
–
–
|
MK
|
|
BRENDA:
BS188596
KEGG:
R02528
MetaCyc:
RXN0-4281
SABIO-RK:
2450
|
|
|
|
H+ + methylglyoxal + NADH <=> Hydroxyacetone + NAD+
|
1.1.1
1.1.1.1
alcohol dehydrogenase
1.1.1.21
aldose reductase
1.1.1.75
(R)-aminopropanol dehydrogenase
|
–
–
–
–
|
K
|
|
BRENDA:
BS188635
KEGG:
R10718
MetaCyc:
RXN0-5213
SABIO-RK:
9806
|
|
|
|
(S)-1,2-Propanediol + NAD+ <=> Hydroxyacetone + NADH + H+
|
1.1.1.406
galactitol 2-dehydrogenase (L-tagatose-forming)
|
–
|
M
|
|
BRENDA:
BS371404
MetaCyc:
RXN-8632
|
|
|
|
Hydroxyacetone + NADH + H+ <=> 1,2-propanediol + NAD+
|
1.1.1.1
alcohol dehydrogenase
1.1.1.165
2-alkyn-1-ol dehydrogenase
1.1.1.4
(R,R)-butanediol dehydrogenase
1.1.1.6
glycerol dehydrogenase
|
–
–
–
–
|
K
|
|
BRENDA:
BS165099
KEGG:
R10717
|
|
|
|
1,2-propanediol + NADP+ <=> Hydroxyacetone + NADPH
|
1.1.1.1
alcohol dehydrogenase
1.1.1.156
glycerol 2-dehydrogenase (NADP+)
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.21
aldose reductase
|
–
–
–
–
|
|
|
BRENDA:
BS187342
SABIO-RK:
10434
|
|
|
|
ATP + Hydroxyacetone <=> ADP + Hydroxyacetone_phosphate
|
2.7.1.29
glycerone kinase
|
–
|
|
|
BRENDA:
BS357437
SABIO-RK:
15486
|
|
|
|
pyruvate + formaldehyde + H+ <=> Hydroxyacetone + CO2
|
not assigned
|
–
|
|
|
MetaCyc:
RXN-10065
|
|
|
|
acetone + O2 + NADH + H+ <=> Hydroxyacetone + NAD+ + H2O
|
1.14.13.M31
|
–
|
M
|
|
MetaCyc:
RXN-17569
|
|
|
|
Hydroxyacetone + O2 + NADPH + H+ <=> hydroxymethylene_acetate + H2O + NADP+
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-17578
|
|
|
|
Hydroxyacetone + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1,1-dihydroxypropan-2-one + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-17625
|
|
|
|
Hydroxyacetone + O2 + reduced_[NADPH-hemoprotein_reductase] <=> methylglyoxal + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.1
unspecific monooxygenase
|
–
|
|
|
MetaCyc:
RXN-17627
|
|
|
|
acetone + reduced_[NADPH-hemoprotein_reductase] + O2 <=> Hydroxyacetone + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.1
unspecific monooxygenase
|
–
|
M
|
|
MetaCyc:
RXN-8630
|
|
|
|
Hydroxyacetone + O2 + NADPH <=> acetate + formaldehyde + H2O + NADP+
|
1.14.13.M34
|
–
|
|
|
MetaCyc:
RXN-8633
|
|
|
|
2-Nitro-1-propanol + O2 <=> Hydroxyacetone + nitrite
|
1.13.12.16
nitronate monooxygenase
|
–
|
|
|
BRENDA:
BS355915
|
|
|
|
Hydroxyacetone + O2 <=> methylglyoxal + H2O2
|
1.1.3.9
galactose oxidase
|
–
|
|
|
BRENDA:
BS257703
|
|
|
|
Hydroxyacetone + phenyl_[(2S)-1-oxopropan-2-yl]carbamate <=> phenyl_[(2S,3R,4S)-3,4-dihydroxy-5-oxohexan-2-yl]carbamate
|
4.1.2.13
fructose-bisphosphate aldolase
|
–
|
|
|
BRENDA:
BS428694
|
|
|
|
Hydroxyacetone + phenyl_[(2R)-1-oxopropan-2-yl]carbamate <=> phenyl_[(2R,3R,4S)-3,4-dihydroxy-5-oxohexan-2-yl]carbamate
|
4.1.2.13
fructose-bisphosphate aldolase
|
–
|
|
|
BRENDA:
BS428693
|
|
|
|
(R)-1,2-Propanediol + NAD+ <=> Hydroxyacetone + NADH + H+
|
1.1.1.4
(R,R)-butanediol dehydrogenase
1.1.1.6
glycerol dehydrogenase
|
–
–
|
|
|
BRENDA:
BS422212
|
|
|
|
(S)-Phenylalaninol + H2O + NAD+ <=> Hydroxyacetone + NADH + NH3
|
1.4.1.20
phenylalanine dehydrogenase
|
–
|
|
|
BRENDA:
BS232348
|
|
|
|
Hydroxyacetone + NADPH + H+ <=> glycerol + NADP+
|
1.1.1.184
carbonyl reductase (NADPH)
|
–
|
|
|
BRENDA:
BS423682
|
|
|
|
Hydroxyacetone + NADH <=> 1,2-propanediol
|
1.1.1.4
(R,R)-butanediol dehydrogenase
|
–
|
|
|
BRENDA:
BS165105
|
|
|
|
thiophene-2-carbaldehyde + Hydroxyacetone <=> (3R,4R)-3,4-dihydroxy-4-(thiophen-2-yl)butan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS450753
|
|
|
|
2-nitrobenzaldehyde + Hydroxyacetone <=> (3R,4S)-3,4-dihydroxy-4-(2-nitrophenyl)butan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449265
|
|
|
|
3-Nitrobenzaldehyde + Hydroxyacetone <=> (3R,4S)-3,4-dihydroxy-4-(3-nitrophenyl)butan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449288
|
|
|
|
4-methylbenzaldehyde + Hydroxyacetone <=> (3R,4S)-3,4-dihydroxy-4-(4-methylphenyl)butan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449321
|
|
|
|
4-nitrobenzaldehyde + Hydroxyacetone <=> (3R,4S)-3,4-dihydroxy-4-(4-nitrophenyl)butan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449329
|
|
|
|
1-naphthaldehyde + Hydroxyacetone <=> (3R,4S)-3,4-dihydroxy-4-(naphthalen-1-yl)butan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS450403
|
|
|
|
benzaldehyde + Hydroxyacetone <=> (3R,4S)-3,4-dihydroxy-4-phenylbutan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449632
|
|
|
|
4-trifluoromethylbenzaldehyde + Hydroxyacetone <=> (3R,4S)-3,4-dihydroxy-4-[4-(trifluoromethyl)phenyl]butan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449308
|
|
|
|
Isovaleraldehyde + Hydroxyacetone <=> (3R,4S)-3,4-dihydroxy-6-methylheptan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449286
|
|
|
|
2,6-dichlorobenzaldehyde + Hydroxyacetone <=> (3R,4S)-4-(2,6-dichlorophenyl)-3,4-dihydroxybutan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449195
|
|
|
|
2-Chlorobenzaldehyde + Hydroxyacetone <=> (3R,4S)-4-(2-chlorophenyl)-3,4-dihydroxybutan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449258
|
|
|
|
3-bromobenzaldehyde + Hydroxyacetone <=> (3R,4S)-4-(3-bromophenyl)-3,4-dihydroxybutan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449278
|
|
|
|
4-bromobenzaldehyde + Hydroxyacetone <=> (3R,4S)-4-(4-bromophenyl)-3,4-dihydroxybutan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449310
|
|
|
|
4-Chlorobenzaldehyde + Hydroxyacetone <=> (3R,4S)-4-(4-chlorophenyl)-3,4-dihydroxybutan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449313
|
|
|
|
4-Fluorobenzaldehyde + Hydroxyacetone <=> (3R,4S)-4-(4-fluorophenyl)-3,4-dihydroxybutan-2-one
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449317
|
|
|
|
4-cyanobenzaldehyde + Hydroxyacetone <=> 4-[(1S,2R)-1,2-dihydroxy-3-oxobutyl]benzonitrile
|
3.4.23.1
pepsin A
|
–
|
|
|
BRENDA:
BS449318
|
|
|
|
cyanide + Hydroxyacetone <=> (2R)-1,2-dihydroxy-2-methyl-propane-3-nitrile
|
4.1.2.46
aliphatic (R)-hydroxynitrile lyase
|
–
|
|
|
BRENDA:
BS409064
|
|
|
|
veratryl_alcohol + Hydroxyacetone <=> 1,2-propanediol + 3,4-dimethoxybenzaldehyde
|
1.1.99.36
alcohol dehydrogenase (nicotinoprotein)
|
–
|
|
|
SABIO-RK:
14287
|
|
|
|
methylglyoxal + veratryl_alcohol <=> Hydroxyacetone + 3,4-dimethoxybenzaldehyde
|
1.1.99.36
alcohol dehydrogenase (nicotinoprotein)
|
–
|
|
|
SABIO-RK:
14285
|
|